Intercomparison of NO column measurements during MAP/GLOBUS 1985     

R. L. McKenzie  W. A. Matthews  Y. Kondo  R. Zander  Ph. Demoulin  P. Fabian  D. G. Murcray  F. J. Murcray  O. Lado-Bordowsky  C. Camy-Peyret  H. K. Roscoe  J. A. Pyle  R. D. McPeters 《Journal of Atmospheric Chemistry》1988,7(4):353-367

Column measurements of nitric oxide were made using several techniques during the MAP/GLOBUS campaign in France in September 1985. The data sets are nearly co-located and simultaneous, therefore allowing a valid intercomparison of the various measurement methods. The range of altitudes sampled differs from instrument to instrument. This complicates the comparison because the data sets are to some extent complementary. The NO distributions apparently vary significantly from day to day, and possibly over shorter timescales. Changes in dynamics may be responsible for these variations. The results from the instruments which measure in the infrared and the ultraviolet are self-consistent, and show good agreement with photochemical predictions. On 19 September, when the intercomparison was made, the profile measured by the in-situ chemiluminescent instrument differed significantly from the predicted profile, and the measured columns were generally higher.  相似文献   

Melting and continent generation     

R.K. O''Nions  D.P. McKenzie 《Earth and Planetary Science Letters》1988,90(4):449-456

The fractionated rare earth distribution in the continents requires that a small melt fraction ( 1%) separates at some stage in their development, either in the crust or in the mantle, and carries with it the continental budget of those elements. It is proposed that the very small melt fractions which control the continent's fractionated trace element budget are generated in response to lithospheric extension, plumes or aqueous fluids beneath island arcs, and emplaced into the deeper parts of the continental lithosphere. This budget is subsequently inherited by granite melts which only separate on relevant geological time scales when melt fractions reach 10% or more. The residence times of trace incompatible and major elements in the continents might be quite different.  相似文献   

A multidisciplinary approach to evaluating impacts of shellfish aquaculture on benthic communities     

J. Grant  A. Hatcher  D. B. Scott  P. Pocklington  C. T. Schafer  G. V. Winters 《Estuaries and Coasts》1995,18(1):124-144

The impact of suspended mussel culture (Mytilus edulis, M. trossulus) on the benthos of a small Nova Scotia cove (7 m depth) was assessed using meehods involving both benthic metabolism and community structure. Due to deposition of mussel feces and pseudofeces, sedimentation rate was higher under the mussel culture lines than at an adjacent reference site of similar sediment texture. Porewater profiles of sediment sulfate and sulfide indicated greater anaerobic metabolism at the mussel site than at the reference site, but sulfide was absent from the upper centimeters of sediments under the mussels. Seasonal measures of sediment oxygen demand showed little change between sites, but maximum rates of ammonium release at the mussel site were twice the highest rates measured at the reference site. Abundance of benthic macrofauna was higher at the reference site, but biomass was generally lower. Biomass at the mussel site was dominated by molluscs (Ilyanassa spp. andNucula tenuisulcata), that were attracted to mussels fallen from the culture and/or enriched organic matter due to biodeposition. Species diversity was lower at the reference site due to the dominance of the polychaeteNephtys neotena. Abundance-biomass comparisons (ABC method) of faunal analysis did not indicate any impact of biodeposition at this site: however, disturbance did not result in a typical assemblage of small opportunistic species anticipated with this method. Cluster analysis of macrofauna usually provided a clear separation between the sites. Since the contruction of a causeway (1968), foraminifera species composition showed a temporal response to temperature changes in the cove by shifting toward calcareous species, but assemblages downcore showed little or no relationship to aquaculture impacts. Although there is a shift toward anaerobic metabolism at the mussel lines, the impact of mussels falling to the sediments was more noticeable in benthic community structure than was any impact due to organic sedimentation or hypoxia. In general the impact of aquaculture on the benthos appeared to be minor. Furtyher assesment of these consequences may mandate both taxonomic and energetic approaches to impact assessment.  相似文献   

Distribution of Volatile Organic Compounds in a New Jersey Coastal Plain Aquifer System     

Thomas V. Fusillo  Joseph J. Hochreiter  Jr.  Deborah Grant Lord 《Ground water》1985,23(3):354-360

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Cathodoluminescence petrography of syntectonic quartz fibres     

Dorothee Dietrich  Paul R. Grant 《Journal of Structural Geology》1985,7(5):541-553

The cathodoluminescence of low grade metamorphic quartz is reported in the literature to be uniformly brown. This study describes an investigation of syntectonic quartz fibres from veins and pressure shadows contained in different carbonate units of the Helvetic Alps, Switzerland, and of Anglesey, U.K., with the Scanning Electron Microscope in the cathodoluminescence mode. The cathodoluminescence spectra measured show systematic variations between older and younger parts of the same fibre, and between fibres from different tectonic units. These variations can be related first to variations in the temperature of formation of the quartz fibres, and second to deformation-induced differences in the microstructure of the earlier formed parts of fibres during later imposed strains.  相似文献   

Effect of treatment with reserpine on the change in filtration rate of Mytilus edulis subjected to dissolved copper     

Richard Howell  Alasdair M. Grant  Norman E.J. Maccoy 《Marine pollution bulletin》1984,15(12):436-439

Exposure of specimens of Mytilus edulis to dissolved copper leads to a fall in the filtration rate measured in whole animals. The copper concentration leading to a 50% reduction in the filtration rate was found to be 0.094 mg I⁻¹. This effect was abolished on depletion of the monoamine content of the animal using reserpine. It is suggested that there may be a chemosensory mechanism present in the animals which responds to increased levels of metals in the seawater leading to a reduction in the rate of ciliary beating and mediated via the branchial nerve.  相似文献   

RbSr and KAr ages of paleozoic glauconites from Ohio—Indiana and Missouri,U.S.A.     

Norman K. Grant  Thomas E. Laskowski  K.A. Foland 《Chemical Geology》1984,46(3):217-239

Glauconite pellets from the Lower Silurian Brassfield Formation on both limbs of the Cincinnati Arch in Ohio and Indiana give a RbSr age of 370 ± 11 Ma, which is substantially younger than the stratigraphic age of the formation. The age is concordantcwith conventional KAr ages of 355 ± 6 and 368 ± 5 Ma for two of the same glauconites. Concordant ages were also obtained from the Viburnum Trend in Missouri, where glauconite pellets from the Davis Formation in an ore-zone collapse structure into the underlying Bonneterre Formation give a RbSr age of 387 ± 21 Ma and conventional KAr ages of 368 ± 5 and 369 ± 5 and 369 ± 5 Ma. A third suite of glauconite from the Bonneterre Formation in the Old Lead Belt ～ 10 km from the nearest ore body has given a RbSr age of 423 ± 7 Ma and slightly older conventional KAr ages of 434 ± 6, 445 ± 6 and 441 ± 11 Ma.Because these glauconite-bearing rocks have been buried to depths of less than 1 km, thermal resetting of the RbSr and KAr systematics appears unlikely. The initial ${}^{87}\text{Sr}{}^{86}\text{Sr}$ ratios of the RbSr isochrons are similar to the ratios for vein- and vug-filling dolomite and calcite. This is consistent with resetting of the RbSr and KAr systems during diagenetic changes which included the isotopic equilibration (perhaps by cation exchange) of the Sr in the glauconite with that in the diagenetic and Mississippi Valley-type ore fluids. This interpretation implies that the age of the Mississippi Valley-type mineralization in the Viburnum Trend is Devonian rather than Carboniferous—Permian as has been inferred from paleomagnetic measurements.Cation-exchange experiments with a dilute Sr-bearing solution and an artificial oilfield brine indicate that glauconite adsorbs large amounts of Sr, some of which is sufficiently strongly attached to the glauconite lattice as to resist leaching with ammonium acetate. The introduction of this strongly attached Sr may be the first step in the resetting of the RbSr systematics of glauconite by cation exchange.  相似文献   

The transport of heat and matter by fluids during metamorphism     

M. J. Bickle  D. McKenzie 《Contributions to Mineralogy and Petrology》1987,95(3):384-392

Non-dimensional solutions to the equations for the combined advective and diffusive one-dimensional transport of heat and solute in a layer are derived for fixed temperature/concentration on the boundaries and initial conditions of a linear gradient across the layer or a step function at the lower boundary. The solutions allow distinction of regimes in which advective or diffusive transport of either heat or solute predominate as a function of fluid flux, time and a length scale. The much lower diffusive coefficients for solute than heat results in a significant range of length scales and fluid flux rates characterised by advection of matter and diffusion of heat. The advective velocity of a component is a function of its fluid:rock partition coefficient. The most rapidly transported tracers which partition largely into the fluid phase, such as He, will travel orders of magnitude faster than heat or compatible solutes such as oxygen. Geochemical profiles in boundary layer regions where both advective and diffusive transport are significant are shown to be particularly informative as to properties of the rocks related to fluid flow such as porosity, permeability, time scales and fluid flux rates. The importance of advection can be directly estimated from the asymmetry of the geochemical profiles across individual layers.  相似文献   

Mt. Pelée, martinique: may 8 and 20, 1902, pyroclastic flows and surges     

Richard V. Fisher  Grant Heiken   《Journal of Volcanology and Geothermal Research》1982,13(3-4)

The distribution, stratigraphic relationships and fragmental components of the May 8 and 20, 1902, pyroclastic flows from Mt. Pelée, Martinique, together with eyewitness accounts, suggest the following explanation for those eruptions. The eruptions were vertically directed magmatic (perhaps initiated phreatically), and contained abundant juvenile lithics from congealed magma of the dome and neck. This resulted in a two-part eruption column having (1) a dense, lithic-charged part which collapsed into the crater and flowed out of a pre-existing notch in its side, giving rise to pyrochlastic flows, and (2) a magmatically derived column containing gases, juvenile vitric material and crystals which largely by-passed the neck and dome and escaped into the atmosphere. All of the energy of the flows was apparently focused through the notch. They emerged fully turbulent and flowed down Rivière Blanche. Gravity segregation of large and abundant fragments soon resulted in a dense, high-concentration, poorly fluidized block-and-ash flow confined to the valley, leaving above a fully turbulent, high-energy ash-cloud surge. As the ash-cloud surge moved down the mountain, it continued to expand outward. The process of gravity segregation continued as the ash-cloud surge expanded, resulting in secondary block-and-ash underflows. Toward St. Pierre, the secondary block-and-ash flows developed on a gently sloping upland surface 100 m or more above the valley of Rivière Blanche. The turbulent, fragment-depleted surges above the secondary block-and-ash flows maintained sufficient energy to devastate the landscape outward to about 3000 m, including St. Pierre. The surges refracted around obstacles and in one place, moved up a small valley in a direction opposite to the main flows.  相似文献   

The scaling of flow in vegetative structures     

Grant  Richard H. 《Boundary-Layer Meteorology》1983,25(2):171-191

Sensible heat flux data obtained from the U.S. Environmental Protection Agency's Regional Air Pollution Study in St. Louis, Missouri are presented and discussed. Large spatial variations exist in heat flux on both a land-use scale and the urban scale. Arguments based upon empirical data and sampling theory show that estimates of heat flux representative of an upwind fetch l _x require a minimum observation height proportional to z ^3/4. The influence of advection on the magnitude of the heat flux is also explored for both the urban and sub-urban or land-use scales. The data clearly indicate that advection can strongly modulate and even dominate the vertical heat flux above surfaces in areas which maintain large horizontal temperature gradients. The advection contribution is positive for cold air advection and negative for warm air advection, and may result from either the urban heat island or land-use mesoscale features. The depth of advective influence is directly proportional to the horizontal scale of the phenomenon and inversely proportional to horizontal temperature gradient.  相似文献